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Malvern Panalytical Scientific Award 2023

Our 2023 Scientific Award is now open – and there’s a €5,000 prize for the best entry.
Entries close August 31st – you’ve still got time!

QUESTION

What materials cannot be analysed using XRF?

XRF cannot detect very light elements, specifically those with an atomic number lower than magnesium, like lithium, beryllium, carbon, or hydrogen. It also struggles with materials that aren't the same all the way through or samples where the surface doesn't match the inside. Because it only identifies elements, it cannot tell you how those elements are chemically bonded together.

Understanding XRF Technology Constraints

The main reason XRF can’t “see” very light elements is that their energy is too weak to reach the detector. This means XRF isn’t the right tool for identifying purely organic things like wood, most plastics, or liquids like oil, because they are mostly made of carbon and hydrogen.

Since XRF only looks at the surface, things like heavy rust, thick paint, or dirt can get in the way of a true reading. If the material is inconsistent—like a piece of concrete with large stones in it—the reading might change depending on exactly where you point the beam.

Finally, XRF tells you the “what” (elements) but not the “how” (molecular structure). For example, it can tell you there is lead in a sample, but it won’t tell you if that lead is part of a specific chemical compound.

Considering XRF for Your Application?

If you want to learn more about the limitations and strengths of this method, visit our XRF technology page.

You can also see how our handheld XRF analysers handle different material types.

If you are unsure if your material can be tested, please contact our team at Portable Analytical Solutions for a technical consultation.

WANT MORE INFO?

Want to find out more? Reach out to our team today, and we’ll be more than happy to help.

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